Spatial and temporal variation in sources of atmospheric nitrogen deposition in the Rocky Mountains using nitrogen isotopes

Leora Nanus, Donald H. Campbell, Christopher M.B. Lehmann, M. Alisa Mast

Research output: Contribution to journalArticle

Abstract

Variation in source areas and source types of atmospheric nitrogen (N) deposition to high-elevation ecosystems in the Rocky Mountains were evaluated using spatially and temporally distributed N isotope data from atmospheric deposition networks for 1995-2016. This unique dataset links N in wet deposition and snowpack to mobile and stationary emissions sources, and enhances understanding of the impacts of anthropogenic activities and environmental policies that mitigate effects of accelerated N cycling across the Rocky Mountain region. δ15N−NO3 at 50 U.S. Geological Survey Rocky Mountain Snowpack (Snowpack) sites ranged from −3.3‰ to +6.5‰ with a mean value of +1.4‰. At 15 National Atmospheric Deposition Program (NADP)/National Trends Network wet deposition (NADP Wetfall) sites, summer δ15N−NO3 is significantly lower ranging from −7.6‰ to −1.3‰ while winter δ15N−NO3 ranges from −2.6‰ to +5.5‰ with a mean value of +0.7‰ during the cool season. The strong seasonal difference in NADP Wetfall δ15N−NO3 is due in part to variation in the proportion of N originating from source regions at different times of the year due to seasonal changes in weather patterns. Snowpack NO3 and δ15N−NO3 are significantly related to NADP Wetfall (fall and winter) suggesting that bulk snowpack samples provide a reliable estimate at high elevations. Spatial trends show higher NO3 concentrations and δ15N−NO3 in the Southern Rocky Mountains located near larger anthropogenic N emission sources compared to the Northern Rocky Mountains. NADP Wetfall δ15N−NH4+ ranged from −10‰ to 0‰ with no observed spatial pattern. However, the lowest δ15N−NH4+(−9‰), and the highest NH4+ concentration (35 μeq/L) were observed at a Utah site dominated by local agricultural activities, whereas the higher δ15N−NH4+ observed in Colorado and Wyoming are likely due to mixed sources, including fossil fuel combustion and agricultural sources. These findings show spatial and seasonal variation in N isotope data that reflect differences in sources of anthropogenic N deposition to high-elevation ecosystems and have important implications for environmental policy across the Rocky Mountain region.

Original languageEnglish (US)
Pages (from-to)110-119
Number of pages10
JournalAtmospheric Environment
Volume176
DOIs
StatePublished - Mar 2018

Keywords

  • Air quality
  • Ammonium
  • Atmospheric deposition
  • Nitrate
  • Nitrogen isotope
  • Rocky Mountains

ASJC Scopus subject areas

  • Environmental Science(all)
  • Atmospheric Science

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