(-)/(+)-Sparteine induced chirally-active carbon nanoparticles for enantioselective separation of racemic mixtures

Gururaja Vulugundam, Santosh K. Misra, Fatemeh Ostadhossein, Aaron S. Schwartz-Duval, Enrique A. Daza, Dipanjan Pan

Research output: Contribution to journalArticle

Abstract

Chiral carbon nanoparticles (CCNPs) were developed by surface passivation using the chiral ligand (-)-sparteine or (+)-sparteine (denoted (-)-SP/CNP and (+)-SP/CNP, respectively). The chirality of the prepared CCNPs was demonstrated by circular dichroism and polarimetry and employed as an enantioselective separation platform for representative racemic mixtures.

Original languageEnglish (US)
Pages (from-to)7513-7516
Number of pages4
JournalChemical Communications
Volume52
Issue number47
DOIs
StatePublished - Jan 1 2016

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ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Vulugundam, G., Misra, S. K., Ostadhossein, F., Schwartz-Duval, A. S., Daza, E. A., & Pan, D. (2016). (-)/(+)-Sparteine induced chirally-active carbon nanoparticles for enantioselective separation of racemic mixtures. Chemical Communications, 52(47), 7513-7516. https://doi.org/10.1039/c6cc02525k