(-)/(+)-Sparteine induced chirally-active carbon nanoparticles for enantioselective separation of racemic mixtures

Gururaja Vulugundam, Santosh K. Misra, Fatemeh Ostadhossein, Aaron S. Schwartz-Duval, Enrique A. Daza, Dipanjan Pan

Research output: Contribution to journalArticle

Abstract

Chiral carbon nanoparticles (CCNPs) were developed by surface passivation using the chiral ligand (-)-sparteine or (+)-sparteine (denoted (-)-SP/CNP and (+)-SP/CNP, respectively). The chirality of the prepared CCNPs was demonstrated by circular dichroism and polarimetry and employed as an enantioselective separation platform for representative racemic mixtures.

Original languageEnglish (US)
Pages (from-to)7513-7516
Number of pages4
JournalChemical Communications
Volume52
Issue number47
DOIs
StatePublished - Jan 1 2016

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Sparteine
Carbon
Nanoparticles
Polarimeters
Chirality
Dichroism
Passivation
Ligands

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

(-)/(+)-Sparteine induced chirally-active carbon nanoparticles for enantioselective separation of racemic mixtures. / Vulugundam, Gururaja; Misra, Santosh K.; Ostadhossein, Fatemeh; Schwartz-Duval, Aaron S.; Daza, Enrique A.; Pan, Dipanjan.

In: Chemical Communications, Vol. 52, No. 47, 01.01.2016, p. 7513-7516.

Research output: Contribution to journalArticle

Vulugundam, Gururaja ; Misra, Santosh K. ; Ostadhossein, Fatemeh ; Schwartz-Duval, Aaron S. ; Daza, Enrique A. ; Pan, Dipanjan. / (-)/(+)-Sparteine induced chirally-active carbon nanoparticles for enantioselective separation of racemic mixtures. In: Chemical Communications. 2016 ; Vol. 52, No. 47. pp. 7513-7516.
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