Sorption of heavy metal cations on rhyolitic and andesitic bentonites from Central Slovakia

Slávka Andrejkovičová, Martin Pentrák, L'Uboš Jankovič, Peter Komadel

Research output: Contribution to journalArticlepeer-review

Abstract

The main purpose of this work was to determine adsorption characteristics of heavy metal cations on two Slovak bentonites. Adsorption of Pb2+, Zn2+, Cu2+ and Cd2+ on Jelšový Potok (JP) and Lieskovec (L) bentonites was studied by the batch equilibration technique using solutions of different concentrations. Higher smectite content (81 mass %) and higher cation exchange capacity (CEC) (105 mmol M+/100 g) of JP bentonite cause higher adsorption of all heavy metals in comparison with L bentonite. JP adsorbed heavy metals in the order Pb2+ [ Cd 2+ > Zn2+ > Cu2+ while sorption on L was slightly different, Pb2+ ] Cd2+ > Cu2+ ≥ Zn2+. The Freundlich model of adsorption is more appropriate for adsorption of Pb2+ and Cd2+ while lower uptake of Cu 2+ and Zn2+ is better described by the Langmuir model. Negative ΔG° values indicate that the adsorption process of all cations on both bentonites is feasible, spontaneous and exothermic. The decrease in the d001 spacings from 14.8-14.9 Å in natural dominantly Ca2+-saturated samples to 13.2-12.6 Å for both bentonites saturated with four heavy metal cations shows the effect of less hydrated exchangeable cations on interlayer spacing. Jelšový Potok bentonite of higher montmorillonite content and greater CEC is the more effective candidate for removal of Pb2+, Zn2+, Cu 2+ and Cd2+ from waste water than Lieskovec bentonite.

Original languageEnglish (US)
Pages (from-to)163-171
Number of pages9
JournalGeologica Carpathica
Volume61
Issue number2
DOIs
StatePublished - Apr 1 2010
Externally publishedYes

Keywords

  • Adsorption isotherm
  • Bentonite
  • Cadmium
  • Copper
  • Lead
  • Zinc

ASJC Scopus subject areas

  • Geology

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