Sonochemistry and sonoluminescence of room-temperature ionic liquids

James D. Oxley, Tanya Prozorov, Kenneth S. Suslick

Research output: Contribution to journalArticlepeer-review

Abstract

The sonication of ionic organic liquids leads to decomposition of the liquids. Multibubble sonoluminescence spectra and headgas analysis reveal a variety of decomposition products from the sonolysis of N,N-dialkylimidazolium ionic liquids. The decomposition is a result of acoustic cavitation, which generates localized hot spots from the implosive collapse of bubbles in the ionic liquids. Despite the negligible vapor pressure of the ionic liquids, reaction still occurs in a heated shell of the bubbles or from microdroplets thrown into the collapsing bubbles.

Original languageEnglish (US)
Pages (from-to)11138-11139
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number37
DOIs
StatePublished - Sep 17 2003

ASJC Scopus subject areas

  • Catalysis
  • General Chemistry
  • Biochemistry
  • Colloid and Surface Chemistry

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