Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants

Camille Boucher-Jacobs; Bo Li; Charles M. Schroeder; Damien Guironnet

doi:10.1039/c9py00154a

Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants

Camille Boucher-Jacobs, Bo Li, Charles M. Schroeder, Damien Guironnet

Research output: Contribution to journal › Article › peer-review

Abstract

Water-soluble phosphinosulfonate palladium complexes were synthesized by coordination of a surfactant to the metal center. The ethylene polymerization activity of the corresponding catalyst was probed. The surfactant and pH of the solution are shown to influence the activity. A phosphated surfactant resulted in polymerization with the highest activity and stability.

Original language	English (US)
Pages (from-to)	1988-1992
Number of pages	5
Journal	Polymer Chemistry
Volume	10
Issue number	16
DOIs	https://doi.org/10.1039/c9py00154a
State	Published - Apr 28 2019

ASJC Scopus subject areas

Bioengineering
Biochemistry
Polymers and Plastics
Organic Chemistry

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title = "Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants",

abstract = "Water-soluble phosphinosulfonate palladium complexes were synthesized by coordination of a surfactant to the metal center. The ethylene polymerization activity of the corresponding catalyst was probed. The surfactant and pH of the solution are shown to influence the activity. A phosphated surfactant resulted in polymerization with the highest activity and stability.",

author = "Camille Boucher-Jacobs and Bo Li and Schroeder, {Charles M.} and Damien Guironnet",

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AU - Boucher-Jacobs, Camille

AU - Li, Bo

AU - Schroeder, Charles M.

AU - Guironnet, Damien

PY - 2019/4/28

Y1 - 2019/4/28

N2 - Water-soluble phosphinosulfonate palladium complexes were synthesized by coordination of a surfactant to the metal center. The ethylene polymerization activity of the corresponding catalyst was probed. The surfactant and pH of the solution are shown to influence the activity. A phosphated surfactant resulted in polymerization with the highest activity and stability.

AB - Water-soluble phosphinosulfonate palladium complexes were synthesized by coordination of a surfactant to the metal center. The ethylene polymerization activity of the corresponding catalyst was probed. The surfactant and pH of the solution are shown to influence the activity. A phosphated surfactant resulted in polymerization with the highest activity and stability.

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JO - Polymer Chemistry

JF - Polymer Chemistry

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Solubility and activity of a phosphinosulfonate palladium catalyst in water with different surfactants

Abstract

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