TY - JOUR
T1 - Silver(I) complexes of 1,4-dicyanobenzene
AU - Venkataraman, D.
AU - Gardner, Geoffrey B.
AU - Covey, Aaron C.
AU - Lee, Stephen
AU - Moore, Jeffrey S.
N1 - Copyright:
Copyright 2017 Elsevier B.V., All rights reserved.
PY - 1996/10/15
Y1 - 1996/10/15
N2 - The crystal structures of the complexes of 1,4-benzenedinitrile with silver(I) trifluoromethanesulfonate, catena-poly[ {μ-(aqua-O,O)-bis[ (trifluoromethanesulfonato-O)silver(I)]}-di-μ-(1,4-benzenedinitrile-N: N′)], [Ag2(CF3O3S)2(C8H 4N2)2(H2O)]n, and catena-poly[[di-μ-(aqua-O,O)-disilver(I)]-μ-(1,4-benzenedinitrile-N: N′) bis(hexafluorophosphate)], [Ag2(C8H4N2)2(H 2O)2]n-(PF6)2n, show that irrespective of the counterion, the basic network formed is that of a chain structure. Water molecules located in the unit cell of these structures bridge a pair of adjacent chains by coordinating to silver(I) resulting in ladder-type motifs.
AB - The crystal structures of the complexes of 1,4-benzenedinitrile with silver(I) trifluoromethanesulfonate, catena-poly[ {μ-(aqua-O,O)-bis[ (trifluoromethanesulfonato-O)silver(I)]}-di-μ-(1,4-benzenedinitrile-N: N′)], [Ag2(CF3O3S)2(C8H 4N2)2(H2O)]n, and catena-poly[[di-μ-(aqua-O,O)-disilver(I)]-μ-(1,4-benzenedinitrile-N: N′) bis(hexafluorophosphate)], [Ag2(C8H4N2)2(H 2O)2]n-(PF6)2n, show that irrespective of the counterion, the basic network formed is that of a chain structure. Water molecules located in the unit cell of these structures bridge a pair of adjacent chains by coordinating to silver(I) resulting in ladder-type motifs.
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U2 - 10.1107/S0108270196006099
DO - 10.1107/S0108270196006099
M3 - Article
AN - SCOPUS:0030259840
SN - 0108-2701
VL - 52
SP - 2416
EP - 2419
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 10
ER -