Seven-Coordinate Titanium and Vanadium Carbonyls: Synthesis and X-ray Crystal Structures of [f-BUSi(CH₂PMe₂)₃]TI(CO)₄and [f-BuSi(CH₂PMe₂)₃]V(CO)₃H

Keyphrases

• Vanadium 100%
• Rutile 100%
• Carbonyl 100%
• X-ray Crystal Structure 100%
• Seven-coordinate 100%
• Ti-C 66%
• Hydrides 33%
• X-ray Crystallography 33%
• Spectroscopic Data 33%
• Phosphine Ligands 33%
• Chelates 33%
• Stretching Force 33%
• Carbon Dioxide 33%
• Octahedron 33%
• Tetrahydrofuran 33%
• Force Constants 33%
• Trigonal Prism 33%
• Phosphine Complexes 33%
• Piano-stool 33%
• Tripod 33%
• Back-donation 33%
• Oxidative Stability 33%
• Kinetic Stability 33%
• Oxidative Carbonylation 33%
• Sodium Naphthalenide 33%
• 13C NMR Chemical Shift 33%

Chemistry

• Crystal Structure 100%
• Vanadium 100%
• Titanium 100%
• Point Group C∞V 66%
• Structure 33%
• Sodium 33%
• Carbon Monoxide 33%
• Tetrahydrofuran 33%
• Chemical Shift 33%
• Substance Spectroscopy 33%
• Octahedral Crystal 33%
• Carbonylation 33%
• 13C NMR Spectroscopy 33%
• Force Constant 33%

Biochemistry, Genetics and Molecular Biology

• X Ray 100%
• Crystal Structure 100%
• Carbonylation 50%