Second-Order Nonlinear Optical Active Calix[4]arene Polyimides Suitable for Frequency Doubling in the UV Region

Paul J.A. Kenis; Oscar F.J. Noordman; Niek F. Van Hulst; Johan F.J. Engbersen; David N. Reinhoudt; Benno H.M. Hams; Cornelis P.J.M. Van Der Vorst

doi:10.1021/cm960420g

Second-Order Nonlinear Optical Active Calix[4]arene Polyimides Suitable for Frequency Doubling in the UV Region

Paul J.A. Kenis, Oscar F.J. Noordman, Niek F. Van Hulst, Johan F.J. Engbersen, David N. Reinhoudt, Benno H.M. Hams, Cornelis P.J.M. Van Der Vorst

Research output: Contribution to journal › Article

Abstract

A new type of soluble calix[4]arene-based polyimides was prepared by reaction of bis(3-aminopropyl) dipropyl functionalized tetranitrocalix[4]arenes with hexafluoroisopropylidene diphthalic anhydride. Spin-coating of these polymers and subsequent electric field poling results in films that are highly transparent above 410 nm and exhibit high and thermally stable second harmonic generation coefficients. These properties make these materials very suitable for frequency-doubling applications in the UV region (820-410 nm).

Original language	English (US)
Pages (from-to)	596-601
Number of pages	6
Journal	Chemistry of Materials
Volume	9
Issue number	2
DOIs	https://doi.org/10.1021/cm960420g
State	Published - Feb 1997
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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10.1021/cm960420g

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Kenis, P. J. A., Noordman, O. F. J., Van Hulst, N. F., Engbersen, J. F. J., Reinhoudt, D. N., Hams, B. H. M., & Van Der Vorst, C. P. J. M. (1997). Second-Order Nonlinear Optical Active Calix[4]arene Polyimides Suitable for Frequency Doubling in the UV Region. Chemistry of Materials, 9(2), 596-601. https://doi.org/10.1021/cm960420g

Second-Order Nonlinear Optical Active Calix[4]arene Polyimides Suitable for Frequency Doubling in the UV Region. / Kenis, Paul J.A.; Noordman, Oscar F.J.; Van Hulst, Niek F.; Engbersen, Johan F.J.; Reinhoudt, David N.; Hams, Benno H.M.; Van Der Vorst, Cornelis P.J.M.

In: Chemistry of Materials, Vol. 9, No. 2, 02.1997, p. 596-601.

Research output: Contribution to journal › Article

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abstract = "A new type of soluble calix[4]arene-based polyimides was prepared by reaction of bis(3-aminopropyl) dipropyl functionalized tetranitrocalix[4]arenes with hexafluoroisopropylidene diphthalic anhydride. Spin-coating of these polymers and subsequent electric field poling results in films that are highly transparent above 410 nm and exhibit high and thermally stable second harmonic generation coefficients. These properties make these materials very suitable for frequency-doubling applications in the UV region (820-410 nm).",

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