Abstract
The statistical mechanics of cross-linked macromolecules requires simultaneous treatment of random polymer configurations, excluded-volume interactions, and the quenched disorder of the cross-links, as well as the topological constraints imposed by impenetrable chains. Such a description was pioneered by Deam and Edwards. This work is reviewed and a discussion presented of subsequent efforts to understand the unique elastic properties of networks as well as the critical phenomena of the vulcanization transition.
| Original language | English (US) |
|---|---|
| Title of host publication | Stealing the Gold |
| Subtitle of host publication | A celebration of the pioneering physics of Sam Edwards |
| Editors | Paul Goldbart, Nigel Goldenfeld, David Sherrington |
| Publisher | Oxford University Press |
| Pages | 275-300 |
| ISBN (Print) | 9780198528531 |
| DOIs | |
| State | Published - Dec 2 2004 |
Keywords
- statistical mechanics
- cross-linked polymers
- cross-linked macromolecules
- polymers
- macromolecules
- rubber
- excluded volume
- vulcanization