Rotationally-resolved spectroscopy of the ν 16 band of 1,3,5-trioxane

Bradley M. Gibson, Nicole C. Koeppen, Benjamin J. McCall

Research output: Contribution to journalArticlepeer-review

Abstract

Rotationally-resolved spectra of the ν16 band of 1,3,5-trioxane, centered near 1177 cm-1, have been obtained via cavity ringdown spectroscopy using a continuous-wave external-cavity quantum cascade laser and a slit expansion nozzle. 219 transitions were identified and fitted to determine the excited state rotational constants for this band. In addition to fundamental interest, these data could facilitate spectroscopic detection of trioxane in cometary comae as a tracer for polyoxymethylene.

Original languageEnglish (US)
Pages (from-to)47-49
Number of pages3
JournalJournal of Molecular Spectroscopy
Volume317
DOIs
StatePublished - Nov 1 2015

Keywords

  • Cavity ringdown spectroscopy
  • Quantum cascade laser
  • Trioxane

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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