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Role of a guanidinium cation-phosphodianion pair in stabilizing the vinyl carbanion intermediate of orotidine 5′-phosphate decarboxylase-catalyzed reactions

  • Bogdana Goryanova
  • , Lawrence M. Goldman
  • , Tina L. Amyes
  • , John A. Gerlt
  • , John P. Richard

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Chemistry

Biochemistry, Genetics and Molecular Biology