@article{ebfcc74069784fdcaabac3fc95655475,
title = "Rheology, crystal structure, and nanomechanical properties in large-scale additive manufacturing of polyphenylene sulfide/carbon fiber composites",
abstract = "Extrusion based high-throughput Additive Manufacturing (AM) provides a rapid and versatile approach for producing complex structures by using a variety of polymer materials. An underexplored aspect of this technique is concerned with the formation of interfaces between successively deposited layers. This is particularly important for large-scale additive manufacturing of semi-crystalline polymers because of the highly non-isothermal conditions involved, which influence both nucleation and crystal growth. The objective of this work is to investigate the microstructure and the corresponding viscoelastic properties of carbon fiber (CF) reinforced polyphenylene sulfide (PPS) resulting from extrusion-based high-throughput AM process. Questions on development of morphology focus on polymer crystal structure and carbon fiber orientation in the vicinity of the interface between successive layers. This study attempts to establish a fundamental understanding of the role of the AM has in transferring a set of intrinsic material properties to the macroscopic properties of the final AM structure.",
keywords = "Additive manufacturing, Carbon fiber, High-performance polymers, Interface, Semicrystalline polymer",
author = "Peng Liu and Dinwiddie, {Ralph B.} and Keum, {Jong K.} and Vasudevan, {Rama K.} and Stephen Jesse and Nguyen, {Ngoc A.} and Lindahl, {John M.} and Vlastimil Kunc",
note = "Funding Information: Research sponsored by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office, under contract DE-AC05-00OR22725 with UT-Battelle, LLC. The AFM portion of this study was conducted at the Center for Nanophase Materials Sciences, which also provided support (SJ, RKV) and is a DOE Office of Science User Facility. The authors appreciate Cincinnati, Inc. for providing the additive manufacturing equipment for conducting this research. We appreciate Techmer PM, LLC for preparing the materials that are used for this study. We thank Professor Brett Compton and Professor Chad Duty of University of Tennessee, Knoxville for the use of analytical instruments. The authors appreciate Abbey McAlister for conducting the AFM data analysis. We thank Professor Hung-Jue Sue from Texas A&M University for useful discussion of the DMA results. Funding Information: Research sponsored by the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office , under contract DE-AC05-00OR22725 with UT-Battelle, LLC. The AFM portion of this study was conducted at the Center for Nanophase Materials Sciences, which also provided support (SJ, RKV) and is a DOE Office of Science User Facility. The authors appreciate Cincinnati, Inc. for providing the additive manufacturing equipment for conducting this research. We appreciate Techmer PM, LLC for preparing the materials that are used for this study. We thank Professor Brett Compton and Professor Chad Duty of University of Tennessee , Knoxville for the use of analytical instruments. The authors appreciate Abbey McAlister for conducting the AFM data analysis. We thank Professor Hung-Jue Sue from Texas A&M University for useful discussion of the DMA results. Publisher Copyright: {\textcopyright} 2018",
year = "2018",
month = nov,
day = "10",
doi = "10.1016/j.compscitech.2018.09.010",
language = "English (US)",
volume = "168",
pages = "263--271",
journal = "Composites Science and Technology",
issn = "0266-3538",
publisher = "Elsevier BV",
}