Reversible carbonylation of a rhodium(I) complex of o-(diphenylphosphino)N,N-dimethylaniline involving displacement of the dimethylamino arm of the chelate

T. Rauchfuss, D. M. Roundhill

Research output: Contribution to journalArticle

Abstract

The coordinately unsaturated complex [Rh{(o-diphenylphosphino)-N,N-dimethylaniline }2]PF6 is described. This compound reversibly adds CO to form [Rh(PN)2(CO)2] PF6 with the concomitant dissociation of the dimethylamino arms of the chelate.

Original languageEnglish (US)
Pages (from-to)C30-C32
JournalJournal of Organometallic Chemistry
Volume59
Issue numberC
DOIs
StatePublished - Oct 1 1973

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Carbonylation
Rhodium
Carbon Monoxide
rhodium
chelates
dissociation
N,N-dimethylaniline

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Reversible carbonylation of a rhodium(I) complex of o-(diphenylphosphino)N,N-dimethylaniline involving displacement of the dimethylamino arm of the chelate. / Rauchfuss, T.; Roundhill, D. M.

In: Journal of Organometallic Chemistry, Vol. 59, No. C, 01.10.1973, p. C30-C32.

Research output: Contribution to journalArticle

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