Reversible carbonylation of a rhodium(I) complex of o-(diphenylphosphino)N,N-dimethylaniline involving displacement of the dimethylamino arm of the chelate

T. Rauchfuss; D. M. Roundhill

doi:10.1016/S0022-328X(00)95010-1

Reversible carbonylation of a rhodium(I) complex of o-(diphenylphosphino)N,N-dimethylaniline involving displacement of the dimethylamino arm of the chelate

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Abstract

The coordinately unsaturated complex [Rh{(o-diphenylphosphino)-N,N-dimethylaniline }₂]PF₆ is described. This compound reversibly adds CO to form [Rh(PN)₂(CO)₂] PF₆ with the concomitant dissociation of the dimethylamino arms of the chelate.

Original language	English (US)
Pages (from-to)	C30-C32
Journal	Journal of Organometallic Chemistry
Volume	59
Issue number	C
DOIs	https://doi.org/10.1016/S0022-328X(00)95010-1
State	Published - Oct 1 1973
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(00)95010-1

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title = "Reversible carbonylation of a rhodium(I) complex of o-(diphenylphosphino)N,N-dimethylaniline involving displacement of the dimethylamino arm of the chelate",

abstract = "The coordinately unsaturated complex [Rh{(o-diphenylphosphino)-N,N-dimethylaniline }2]PF6 is described. This compound reversibly adds CO to form [Rh(PN)2(CO)2] PF6 with the concomitant dissociation of the dimethylamino arms of the chelate.",

author = "T. Rauchfuss and Roundhill, {D. M.}",

note = "Funding Information: We wish to thank Dr. R.D. Stephens for many helpful discussions. This investigation was supported in part by funds provided by the Graduate School Research Fund. Copyright: Copyright 2014 Elsevier B.V., All rights reserved.",

year = "1973",

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day = "1",

doi = "10.1016/S0022-328X(00)95010-1",

language = "English (US)",

volume = "59",

pages = "C30--C32",

journal = "Journal of Organometallic Chemistry",

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TY - JOUR

T1 - Reversible carbonylation of a rhodium(I) complex of o-(diphenylphosphino)N,N-dimethylaniline involving displacement of the dimethylamino arm of the chelate

AU - Rauchfuss, T.

AU - Roundhill, D. M.

N1 - Funding Information: We wish to thank Dr. R.D. Stephens for many helpful discussions. This investigation was supported in part by funds provided by the Graduate School Research Fund. Copyright: Copyright 2014 Elsevier B.V., All rights reserved.

PY - 1973/10/1

Y1 - 1973/10/1

N2 - The coordinately unsaturated complex [Rh{(o-diphenylphosphino)-N,N-dimethylaniline }2]PF6 is described. This compound reversibly adds CO to form [Rh(PN)2(CO)2] PF6 with the concomitant dissociation of the dimethylamino arms of the chelate.

AB - The coordinately unsaturated complex [Rh{(o-diphenylphosphino)-N,N-dimethylaniline }2]PF6 is described. This compound reversibly adds CO to form [Rh(PN)2(CO)2] PF6 with the concomitant dissociation of the dimethylamino arms of the chelate.

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DO - 10.1016/S0022-328X(00)95010-1

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SN - 0022-328X

VL - 59

SP - C30-C32

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - C

ER -

Reversible carbonylation of a rhodium(I) complex of o-(diphenylphosphino)N,N-dimethylaniline involving displacement of the dimethylamino arm of the chelate

Abstract

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