Response to the rebuttal of the article Pathological crystal structures

Kenneth N. Raymond; Gregory S. Girolami

doi:10.1107/S2053229623010732

Response to the rebuttal of the article Pathological crystal structures

Research output: Contribution to journal › Article › peer-review

Abstract

We stand fully behind our earlier suggestion [Raymond & Girolami (2023). Acta Cryst. C79, 445–455] that the claim by Fish and co-workers [Chen et al. (1995). J. Am. Chem. Soc. 117, 9097–9098; Smith et al. (2014). Organometallics, 33, 2389–2404] of a linear two-coordinate rhodium(I) species is incorrect, and that the putative rhodium atom is in fact silver.

Original language	English (US)
Pages (from-to)	258-261
Number of pages	4
Journal	Acta Crystallographica Section C: Structural Chemistry
Volume	80
DOIs	https://doi.org/10.1107/S2053229623010732
State	Published - Jul 1 2024
Externally published	Yes

Keywords

atom misassignment
crystallographic errors

ASJC Scopus subject areas

Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Online availability

10.1107/S2053229623010732

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AB - We stand fully behind our earlier suggestion [Raymond & Girolami (2023). Acta Cryst. C79, 445–455] that the claim by Fish and co-workers [Chen et al. (1995). J. Am. Chem. Soc. 117, 9097–9098; Smith et al. (2014). Organometallics, 33, 2389–2404] of a linear two-coordinate rhodium(I) species is incorrect, and that the putative rhodium atom is in fact silver.

KW - atom misassignment

KW - crystallographic errors

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ER -

Response to the rebuttal of the article Pathological crystal structures

Abstract

Keywords

ASJC Scopus subject areas

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