TY - JOUR
T1 - Relativistic corrections for methylene
AU - Davidson, Ernest R.
AU - Feller, David
AU - Phillips, Philip
N1 - Copyright:
Copyright 2018 Elsevier B.V., All rights reserved.
PY - 1980/12/15
Y1 - 1980/12/15
N2 - The mass-velocity, Darwin, and magnetic corrections to the 3P-5S and s2p2-sp3 splitting of carbon and the 3B1-1A1 splitting in CH2 have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm-1 for 3P-5S, 100 cm-1 for the s2p2-sp3 configuration average and 15 cm-1 for 3B1-1A1.
AB - The mass-velocity, Darwin, and magnetic corrections to the 3P-5S and s2p2-sp3 splitting of carbon and the 3B1-1A1 splitting in CH2 have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm-1 for 3P-5S, 100 cm-1 for the s2p2-sp3 configuration average and 15 cm-1 for 3B1-1A1.
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U2 - 10.1016/0009-2614(80)80638-5
DO - 10.1016/0009-2614(80)80638-5
M3 - Article
AN - SCOPUS:0011016901
VL - 76
SP - 416
EP - 417
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 3
ER -