Relativistic corrections for methylene

Ernest R. Davidson; David Feller; Philip Phillips

doi:10.1016/0009-2614(80)80638-5

Relativistic corrections for methylene

Ernest R. Davidson, David Feller, Philip Phillips

Research output: Contribution to journal › Article › peer-review

Abstract

The mass-velocity, Darwin, and magnetic corrections to the ³P-⁵S and s²p²-sp³ splitting of carbon and the ³B₁-¹A₁ splitting in CH₂ have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm^-1 for ³P-⁵S, 100 cm^-1 for the s²p²-sp³ configuration average and 15 cm^-1 for ³B₁-¹A₁.

Original language	English (US)
Pages (from-to)	416-417
Number of pages	2
Journal	Chemical Physics Letters
Volume	76
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(80)80638-5
State	Published - Dec 15 1980
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Relativistic corrections for methylene",

abstract = "The mass-velocity, Darwin, and magnetic corrections to the 3P-5S and s2p2-sp3 splitting of carbon and the 3B1-1A1 splitting in CH2 have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm-1 for 3P-5S, 100 cm-1 for the s2p2-sp3 configuration average and 15 cm-1 for 3B1-1A1.",

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AU - Davidson, Ernest R.

AU - Feller, David

AU - Phillips, Philip

PY - 1980/12/15

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N2 - The mass-velocity, Darwin, and magnetic corrections to the 3P-5S and s2p2-sp3 splitting of carbon and the 3B1-1A1 splitting in CH2 have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm-1 for 3P-5S, 100 cm-1 for the s2p2-sp3 configuration average and 15 cm-1 for 3B1-1A1.

AB - The mass-velocity, Darwin, and magnetic corrections to the 3P-5S and s2p2-sp3 splitting of carbon and the 3B1-1A1 splitting in CH2 have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm-1 for 3P-5S, 100 cm-1 for the s2p2-sp3 configuration average and 15 cm-1 for 3B1-1A1.

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Relativistic corrections for methylene

Abstract

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