Relativistic corrections for methylene

Ernest R. Davidson; David Feller; Philip Phillips

doi:10.1016/0009-2614(80)80638-5

Relativistic corrections for methylene

Ernest R. Davidson, David Feller, Philip Phillips

Research output: Contribution to journal › Article › peer-review

Abstract

The mass-velocity, Darwin, and magnetic corrections to the ³P-⁵S and s²p²-sp³ splitting of carbon and the ³B₁-¹A₁ splitting in CH₂ have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm^-1 for ³P-⁵S, 100 cm^-1 for the s²p²-sp³ configuration average and 15 cm^-1 for ³B₁-¹A₁.

Original language	English (US)
Pages (from-to)	416-417
Number of pages	2
Journal	Chemical Physics Letters
Volume	76
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(80)80638-5
State	Published - Dec 15 1980
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

Online availability

10.1016/0009-2614(80)80638-5

Library availability

Discover UIUC Full Text

Cite this

@article{cf07478f9e1e4235b9a31419a4e5b6df,

title = "Relativistic corrections for methylene",

abstract = "The mass-velocity, Darwin, and magnetic corrections to the 3P-5S and s2p2-sp3 splitting of carbon and the 3B1-1A1 splitting in CH2 have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm-1 for 3P-5S, 100 cm-1 for the s2p2-sp3 configuration average and 15 cm-1 for 3B1-1A1.",

author = "Davidson, {Ernest R.} and David Feller and Philip Phillips",

year = "1980",

month = dec,

day = "15",

doi = "10.1016/0009-2614(80)80638-5",

language = "English (US)",

volume = "76",

pages = "416--417",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Relativistic corrections for methylene

AU - Davidson, Ernest R.

AU - Feller, David

AU - Phillips, Philip

PY - 1980/12/15

Y1 - 1980/12/15

N2 - The mass-velocity, Darwin, and magnetic corrections to the 3P-5S and s2p2-sp3 splitting of carbon and the 3B1-1A1 splitting in CH2 have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm-1 for 3P-5S, 100 cm-1 for the s2p2-sp3 configuration average and 15 cm-1 for 3B1-1A1.

AB - The mass-velocity, Darwin, and magnetic corrections to the 3P-5S and s2p2-sp3 splitting of carbon and the 3B1-1A1 splitting in CH2 have been evaluated by first-order perturbation theory. We obtained corrections of 92 cm-1 for 3P-5S, 100 cm-1 for the s2p2-sp3 configuration average and 15 cm-1 for 3B1-1A1.

UR - http://www.scopus.com/inward/record.url?scp=0011016901&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0011016901&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(80)80638-5

DO - 10.1016/0009-2614(80)80638-5

M3 - Article

AN - SCOPUS:0011016901

VL - 76

SP - 416

EP - 417

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 3

ER -

Relativistic corrections for methylene

Abstract

ASJC Scopus subject areas

Online availability

Library availability

Related links

Fingerprint

Cite this