Abstract
The reduction of allylpalladium(II)chloride dimer (APC) to a Pd(0) species can be effected by reaction with alkali metal silanolates. The reduction is extremely rapid in the presence of chelating bisphosphine ligands and for a variety of silanolates.
Original language | English (US) |
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Pages (from-to) | 2921-2928 |
Number of pages | 8 |
Journal | Synlett |
Issue number | 18 |
DOIs | |
State | Published - Nov 3 2006 |
Keywords
- Cross-coupling
- Mechanism
- Palladium
- Reduction
- Silanolate
ASJC Scopus subject areas
- Organic Chemistry