Reduction of allylpalladium(II)chloride dimer by formation of allyloxysilanes

Scott E Denmark, Russell C. Smith

Research output: Contribution to journalArticle

Abstract

The reduction of allylpalladium(II)chloride dimer (APC) to a Pd(0) species can be effected by reaction with alkali metal silanolates. The reduction is extremely rapid in the presence of chelating bisphosphine ligands and for a variety of silanolates.

Original languageEnglish (US)
Pages (from-to)2921-2928
Number of pages8
JournalSynlett
Issue number18
DOIs
StatePublished - Nov 3 2006

Keywords

  • Cross-coupling
  • Mechanism
  • Palladium
  • Reduction
  • Silanolate

ASJC Scopus subject areas

  • Organic Chemistry

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