Abstract
The reduction of allylpalladium(II)chloride dimer (APC) to a Pd(0) species can be effected by reaction with alkali metal silanolates. The reduction is extremely rapid in the presence of chelating bisphosphine ligands and for a variety of silanolates.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2921-2928 |
| Number of pages | 8 |
| Journal | Synlett |
| Issue number | 18 |
| DOIs | |
| State | Published - Nov 3 2006 |
Keywords
- Cross-coupling
- Mechanism
- Palladium
- Reduction
- Silanolate
ASJC Scopus subject areas
- Organic Chemistry
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Cite this
Denmark, S. E., & Smith, R. C. (2006). Reduction of allylpalladium(II)chloride dimer by formation of allyloxysilanes. Synlett, (18), 2921-2928. https://doi.org/10.1055/s-2006-951516