TY - JOUR
T1 - Recovery of Purity in Dissipative Tunneling Dynamics
AU - Chatterjee, Sambarta
AU - Makri, Nancy
N1 - Publisher Copyright:
© 2020 American Chemical Society.
PY - 2020/10/15
Y1 - 2020/10/15
N2 - The time evolution of purity for an initially localized state of a symmetric two-level system coupled to a dissipative bath is investigated using numerically exact real-time path integral methods. With strong system-bath coupling and high temperature, the purity decays monotonically to its fully mixed value, with a short-time Gaussian behavior, which is subsequently followed by exponential evolution. However, under low-temperature and weak coupling conditions, a substantial recovery of purity is observed. A simple theoretical analysis reveals three contributions that correspond to a completely incoherent, eigenstate population difference and rate terms. The last two of these terms can counter the early drop of purity and are responsible for its rebound. These findings caution against using purity as a measure of decoherence in the dynamics of quantum dissipative systems.
AB - The time evolution of purity for an initially localized state of a symmetric two-level system coupled to a dissipative bath is investigated using numerically exact real-time path integral methods. With strong system-bath coupling and high temperature, the purity decays monotonically to its fully mixed value, with a short-time Gaussian behavior, which is subsequently followed by exponential evolution. However, under low-temperature and weak coupling conditions, a substantial recovery of purity is observed. A simple theoretical analysis reveals three contributions that correspond to a completely incoherent, eigenstate population difference and rate terms. The last two of these terms can counter the early drop of purity and are responsible for its rebound. These findings caution against using purity as a measure of decoherence in the dynamics of quantum dissipative systems.
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U2 - 10.1021/acs.jpclett.0c02513
DO - 10.1021/acs.jpclett.0c02513
M3 - Article
C2 - 32976716
AN - SCOPUS:85093539394
SN - 1948-7185
VL - 11
SP - 8592
EP - 8596
JO - Journal of Physical Chemistry Letters
JF - Journal of Physical Chemistry Letters
IS - 20
ER -