Quantifying zinc and manganese reduction potentials in organic solvents

Sagnik Chakrabarti; Liviu M. Mirica

doi:10.1016/j.chempr.2024.10.015

Quantifying zinc and manganese reduction potentials in organic solvents

Research output: Contribution to journal › Comment/debate › peer-review

Abstract

Zinc and manganese are the reductants of choice for nickel-catalyzed cross-electrophile coupling (XEC), but their exact redox potentials are unknown in organic solvents. In a recent report from Stahl and colleagues in Nature Chemistry, these potentials have been measured for the first time and their implications on model XEC reactions have been discussed.

Original language	English (US)
Pages (from-to)	3273-3275
Number of pages	3
Journal	Chem
Volume	10
Issue number	11
DOIs	https://doi.org/10.1016/j.chempr.2024.10.015
State	Published - Nov 14 2024

ASJC Scopus subject areas

General Chemistry
Biochemistry
Environmental Chemistry
General Chemical Engineering
Biochemistry, medical
Materials Chemistry

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10.1016/j.chempr.2024.10.015

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title = "Quantifying zinc and manganese reduction potentials in organic solvents",

abstract = "Zinc and manganese are the reductants of choice for nickel-catalyzed cross-electrophile coupling (XEC), but their exact redox potentials are unknown in organic solvents. In a recent report from Stahl and colleagues in Nature Chemistry, these potentials have been measured for the first time and their implications on model XEC reactions have been discussed.",

author = "Sagnik Chakrabarti and Mirica, {Liviu M.}",

note = "We thank the National Science Foundation (CHE 2155160 to L.M.M.) for financial support.",

year = "2024",

month = nov,

day = "14",

doi = "10.1016/j.chempr.2024.10.015",

language = "English (US)",

volume = "10",

pages = "3273--3275",

journal = "Chem",

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publisher = "Elsevier Inc.",

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TY - JOUR

T1 - Quantifying zinc and manganese reduction potentials in organic solvents

AU - Chakrabarti, Sagnik

AU - Mirica, Liviu M.

N1 - We thank the National Science Foundation (CHE 2155160 to L.M.M.) for financial support.

PY - 2024/11/14

Y1 - 2024/11/14

N2 - Zinc and manganese are the reductants of choice for nickel-catalyzed cross-electrophile coupling (XEC), but their exact redox potentials are unknown in organic solvents. In a recent report from Stahl and colleagues in Nature Chemistry, these potentials have been measured for the first time and their implications on model XEC reactions have been discussed.

AB - Zinc and manganese are the reductants of choice for nickel-catalyzed cross-electrophile coupling (XEC), but their exact redox potentials are unknown in organic solvents. In a recent report from Stahl and colleagues in Nature Chemistry, these potentials have been measured for the first time and their implications on model XEC reactions have been discussed.

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DO - 10.1016/j.chempr.2024.10.015

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Quantifying zinc and manganese reduction potentials in organic solvents

Abstract

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