Pyridyl-cyclopentadiene Re(CO)2+ complexes as a compact core system for SPECT ligand development

Nathan C. Ackroyd; John A. Katzenellenbogen

doi:10.1021/om100521s

Pyridyl-cyclopentadiene Re(CO)₂⁺ complexes as a compact core system for SPECT ligand development

Nathan C. Ackroyd
, John A. Katzenellenbogen

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

An η¹,η⁵-rhenium complex has been prepared, starting from a CpRe(CO)₃ complex substituted with a pendant aromatic amine. This unique complex has potential application as a surrogate for a technetium-99m complex, a common radioisotope for biomedical imaging applications. Chelation occurred via photochemical decarbonylation of the rhenium, which opened a binding site for the aromatic amine.

Original language	English (US)
Pages (from-to)	3669-3671
Number of pages	3
Journal	Organometallics
Volume	29
Issue number	16
DOIs	https://doi.org/10.1021/om100521s
State	Published - Aug 23 2010

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Online availability

10.1021/om100521s

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Cite this

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title = "Pyridyl-cyclopentadiene Re(CO)2+ complexes as a compact core system for SPECT ligand development",

abstract = "An η1,η5-rhenium complex has been prepared, starting from a CpRe(CO)3 complex substituted with a pendant aromatic amine. This unique complex has potential application as a surrogate for a technetium-99m complex, a common radioisotope for biomedical imaging applications. Chelation occurred via photochemical decarbonylation of the rhenium, which opened a binding site for the aromatic amine.",

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