Production of methoxynitrones and stable nitroxyl radicals with gem-dimethoxy groups attached to the α-carbon atom by the oxidation of aldonitrones in methanol

G. I. Shchukin; V. F. Starichenko; I. A. Grigor'ev; S. A. Dikanov; V. I. Gulin; L. B. Volodarskii

doi:10.1007/BF00953858

Production of methoxynitrones and stable nitroxyl radicals with gem-dimethoxy groups attached to the α-carbon atom by the oxidation of aldonitrones in methanol

G. I. Shchukin, V. F. Starichenko, I. A. Grigor'ev, S. A. Dikanov, V. I. Gulin, L. B. Volodarskii

Research output: Contribution to journal › Article

Abstract

1. Imidazoline aldonitrones are spin traps for alkoxy radicals. 2. It has been shown to be possible to obtain preparatively cyclic methoxynitrones and stable nitroxyl radicals with methoxy-groups attached to the α-carbon atom, by the oxidation of cyclic aldonitrones in methanol.

Original language	English (US)
Pages (from-to)	110-115
Number of pages	6
Journal	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Volume	36
Issue number	1
DOIs	https://doi.org/10.1007/BF00953858
State	Published - Jan 1 1987
Externally published	Yes

Fingerprint

Gems

Imidazolines

Methanol

Carbon

Atoms

Oxidation

nitroxyl

alkoxyl radical

ASJC Scopus subject areas

Chemistry(all)

Cite this

Shchukin, G. I., Starichenko, V. F., Grigor'ev, I. A., Dikanov, S. A., Gulin, V. I., & Volodarskii, L. B. (1987). Production of methoxynitrones and stable nitroxyl radicals with gem-dimethoxy groups attached to the α-carbon atom by the oxidation of aldonitrones in methanol. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 36(1), 110-115. https://doi.org/10.1007/BF00953858

Production of methoxynitrones and stable nitroxyl radicals with gem-dimethoxy groups attached to the α-carbon atom by the oxidation of aldonitrones in methanol. / Shchukin, G. I.; Starichenko, V. F.; Grigor'ev, I. A.; Dikanov, S. A.; Gulin, V. I.; Volodarskii, L. B.

In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 36, No. 1, 01.01.1987, p. 110-115.

Research output: Contribution to journal › Article

Shchukin, GI, Starichenko, VF, Grigor'ev, IA, Dikanov, SA, Gulin, VI & Volodarskii, LB 1987, 'Production of methoxynitrones and stable nitroxyl radicals with gem-dimethoxy groups attached to the α-carbon atom by the oxidation of aldonitrones in methanol', Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, vol. 36, no. 1, pp. 110-115. https://doi.org/10.1007/BF00953858

Shchukin GI, Starichenko VF, Grigor'ev IA, Dikanov SA, Gulin VI, Volodarskii LB. Production of methoxynitrones and stable nitroxyl radicals with gem-dimethoxy groups attached to the α-carbon atom by the oxidation of aldonitrones in methanol. Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1987 Jan 1;36(1):110-115. https://doi.org/10.1007/BF00953858

Shchukin, G. I. ; Starichenko, V. F. ; Grigor'ev, I. A. ; Dikanov, S. A. ; Gulin, V. I. ; Volodarskii, L. B. / Production of methoxynitrones and stable nitroxyl radicals with gem-dimethoxy groups attached to the α-carbon atom by the oxidation of aldonitrones in methanol. In: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 1987 ; Vol. 36, No. 1. pp. 110-115.

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10.1007/BF00953858