TY - JOUR
T1 - Prioritization of Early-Stage Research and Development of a Hydrogel-Encapsulated Anaerobic Technology for Distributed Treatment of High Strength Organic Wastewater
AU - Zhang, Xinyi
AU - Arnold, William A.
AU - Wright, Natasha
AU - Novak, Paige J.
AU - Guest, Jeremy S.
N1 - The authors would like to thank Prof. Yalin Li (Rutgers, The State University of New Jersey) for providing insight and help in the computational implementation of the process model. We also thank Gretchen Gutenberger and Ian Song (University of Minnesota Twin Cities) for providing raw experimental data and helpful discussions. This work was funded by the U.S. Department of Energy\u2019s Industrial Efficiency and Decarbonization Office under award number DE-EE0009501c. Any opinions, findings, and conclusions or recommendations expressed in this publication are those of the authors and do not necessarily reflect the views of the U.S. Department of Energy.
PY - 2024/11/5
Y1 - 2024/11/5
N2 - This study aims to support the prioritization of research and development (R&D) pathways of an anaerobic technology leveraging hydrogel-encapsulated biomass to treat high-strength organic industrial wastewaters, enabling decentralized energy recovery and treatment to reduce organic loading on centralized treatment facilities. To characterize the sustainability implications of early-stage design decisions and to delineate R&D targets, an encapsulated anaerobic process model was developed and coupled with design algorithms for integrated process simulation, techno-economic analysis, and life cycle assessment under uncertainty. Across the design space, a single-stage configuration with passive biogas collection was found to have the greatest potential for financial viability and the lowest life cycle carbon emission. Through robust uncertainty and sensitivity analyses, we found technology performance was driven by a handful of design and technological factors despite uncertainty surrounding many others. Hydraulic retention time and encapsulant volume were identified as the most impactful design decisions for the levelized cost and carbon intensity of chemical oxygen demand (COD) removal. Encapsulant longevity, a technological parameter, was the dominant driver of system sustainability and thus a clear R&D priority. Ultimately, we found encapsulated anaerobic systems with optimized fluidized bed design have significant potential to provide affordable, carbon-negative, and distributed COD removal from high strength organic wastewaters if encapsulant longevity can be maintained at 5 years or above.
AB - This study aims to support the prioritization of research and development (R&D) pathways of an anaerobic technology leveraging hydrogel-encapsulated biomass to treat high-strength organic industrial wastewaters, enabling decentralized energy recovery and treatment to reduce organic loading on centralized treatment facilities. To characterize the sustainability implications of early-stage design decisions and to delineate R&D targets, an encapsulated anaerobic process model was developed and coupled with design algorithms for integrated process simulation, techno-economic analysis, and life cycle assessment under uncertainty. Across the design space, a single-stage configuration with passive biogas collection was found to have the greatest potential for financial viability and the lowest life cycle carbon emission. Through robust uncertainty and sensitivity analyses, we found technology performance was driven by a handful of design and technological factors despite uncertainty surrounding many others. Hydraulic retention time and encapsulant volume were identified as the most impactful design decisions for the levelized cost and carbon intensity of chemical oxygen demand (COD) removal. Encapsulant longevity, a technological parameter, was the dominant driver of system sustainability and thus a clear R&D priority. Ultimately, we found encapsulated anaerobic systems with optimized fluidized bed design have significant potential to provide affordable, carbon-negative, and distributed COD removal from high strength organic wastewaters if encapsulant longevity can be maintained at 5 years or above.
KW - anaerobic treatment
KW - biogas recovery
KW - biomass immobilization
KW - greenhouse gas (GHG) emissions
KW - hydrogel encapsulation
KW - quantitative sustainable design
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U2 - 10.1021/acs.est.4c05389
DO - 10.1021/acs.est.4c05389
M3 - Article
C2 - 39460990
AN - SCOPUS:85207724352
SN - 0013-936X
VL - 58
SP - 19651
EP - 19665
JO - Environmental Science and Technology
JF - Environmental Science and Technology
IS - 44
ER -