Polar domains on globular macromolecules: Shape-persistent, amphiphilic tridendrons

Douglas J. Pesak; Jeffrey S. Moore

doi:10.1016/S0040-4020(97)00966-6

Polar domains on globular macromolecules: Shape-persistent, amphiphilic tridendrons

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Abstract

A series of asymmetric phenylacetylene tridendrons is prepared by coupling polar monodendrons having t-butyl esters on their periphery with a non-polar monodendron having t-butyl groups on its periphery. Subsequent conversion of the t-butyl esters to carboxylic acids by thermolysis gives amphiphilic dendrimers having polar domains of various size. The characterization and solution phase behavior of these structures is discussed.

Original language	English (US)
Pages (from-to)	15331-15347
Number of pages	17
Journal	Tetrahedron
Volume	53
Issue number	45
DOIs	https://doi.org/10.1016/S0040-4020(97)00966-6
State	Published - Nov 10 1997

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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AU - Moore, Jeffrey S.

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N2 - A series of asymmetric phenylacetylene tridendrons is prepared by coupling polar monodendrons having t-butyl esters on their periphery with a non-polar monodendron having t-butyl groups on its periphery. Subsequent conversion of the t-butyl esters to carboxylic acids by thermolysis gives amphiphilic dendrimers having polar domains of various size. The characterization and solution phase behavior of these structures is discussed.

AB - A series of asymmetric phenylacetylene tridendrons is prepared by coupling polar monodendrons having t-butyl esters on their periphery with a non-polar monodendron having t-butyl groups on its periphery. Subsequent conversion of the t-butyl esters to carboxylic acids by thermolysis gives amphiphilic dendrimers having polar domains of various size. The characterization and solution phase behavior of these structures is discussed.

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Polar domains on globular macromolecules: Shape-persistent, amphiphilic tridendrons

Abstract

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