Phthalocyanine-based electrically conductive, processible molecular/macromolecular hybrid materials

Tamotsu Inabe; Wen Bin Liang; Joseph F. Lomax; Shuhei Nakamura; Joseph W. Lyding; William J. McCarthy; Stephen H. Carr; Carl R. Kannewurf; Tobin J. Marks

doi:10.1016/0379-6779(86)90072-X

Phthalocyanine-based electrically conductive, processible molecular/macromolecular hybrid materials

Tamotsu Inabe, Wen Bin Liang, Joseph F. Lomax, Shuhei Nakamura, Joseph W. Lyding, William J. McCarthy, Stephen H. Carr, Carl R. Kannewurf, Tobin J. Marks

Research output: Contribution to journal › Article › peer-review

Abstract

This contribution relates new information on the properties of electrically conductive, processible Ni(Pc)/polymer/I₂ hybrid materials. Both the temperature and composition dependence of the electrical conductivity of Ni(Pc)/Kevlar/I₂ fibres are strongly reminiscent of the behaviour of composites. Using a variant of our fibre spinning methodology, it is also possible to produce Ni(Pc)/Kevlar/I₂ ribbons. Polarized resonance Raman spectroscopy indicates that the ribbons are structurally anisotropic (Ni(Pc)I c axes are preferentially aligned in the extrusion direction), while four-probe transport measurements indicate significant anisotropy in the conductivity ( σ_{{norm of matrix}} σ_hu ≈ 8 where {norm of matrix} denotes the extrusion direction). This anisotropy is nearly temperature independent. Electrically conductive fibres can also be prepared using Nomex or poly(p-phenylene-2,6-benzobisthiazole) (PBT) instead of Kevlar as the host polymer.

Original language	English (US)
Pages (from-to)	219-229
Number of pages	11
Journal	Synthetic Metals
Volume	13
Issue number	1-3
DOIs	https://doi.org/10.1016/0379-6779(86)90072-X
State	Published - Jan 1986
Externally published	Yes

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/0379-6779(86)90072-X

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title = "Phthalocyanine-based electrically conductive, processible molecular/macromolecular hybrid materials",

abstract = "This contribution relates new information on the properties of electrically conductive, processible Ni(Pc)/polymer/I2 hybrid materials. Both the temperature and composition dependence of the electrical conductivity of Ni(Pc)/Kevlar/I2 fibres are strongly reminiscent of the behaviour of composites. Using a variant of our fibre spinning methodology, it is also possible to produce Ni(Pc)/Kevlar/I2 ribbons. Polarized resonance Raman spectroscopy indicates that the ribbons are structurally anisotropic (Ni(Pc)I c axes are preferentially aligned in the extrusion direction), while four-probe transport measurements indicate significant anisotropy in the conductivity ( σ{norm of matrix} σhu ≈ 8 where {norm of matrix} denotes the extrusion direction). This anisotropy is nearly temperature independent. Electrically conductive fibres can also be prepared using Nomex or poly(p-phenylene-2,6-benzobisthiazole) (PBT) instead of Kevlar as the host polymer.",

author = "Tamotsu Inabe and Liang, {Wen Bin} and Lomax, {Joseph F.} and Shuhei Nakamura and Lyding, {Joseph W.} and McCarthy, {William J.} and Carr, {Stephen H.} and Kannewurf, {Carl R.} and Marks, {Tobin J.}",

note = "Funding Information: This researchw as supportedb y the Office of Naval Researchb, y the Air Force Office of ScientificR esearch(P BT work, ContractA FOSR-84-0354), and by the NSF-MRL programmteh rought he MaterialsR esearch Centero f NorthwesterUnn iversity( GrantD MR82-16972)W. e thankD rs. Marilyn HunsackerI,v an Goldfarb and Ted Helminiako f the Air Force MaterialsL aboratorfyo r a sampleo f and adviceo n handlingP BT.",

year = "1986",

month = jan,

doi = "10.1016/0379-6779(86)90072-X",

language = "English (US)",

volume = "13",

pages = "219--229",

journal = "Synthetic Metals",

issn = "0379-6779",

publisher = "Elsevier B.V.",

number = "1-3",

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TY - JOUR

T1 - Phthalocyanine-based electrically conductive, processible molecular/macromolecular hybrid materials

AU - Inabe, Tamotsu

AU - Liang, Wen Bin

AU - Lomax, Joseph F.

AU - Nakamura, Shuhei

AU - Lyding, Joseph W.

AU - McCarthy, William J.

AU - Carr, Stephen H.

AU - Kannewurf, Carl R.

AU - Marks, Tobin J.

N1 - Funding Information: This researchw as supportedb y the Office of Naval Researchb, y the Air Force Office of ScientificR esearch(P BT work, ContractA FOSR-84-0354), and by the NSF-MRL programmteh rought he MaterialsR esearch Centero f NorthwesterUnn iversity( GrantD MR82-16972)W. e thankD rs. Marilyn HunsackerI,v an Goldfarb and Ted Helminiako f the Air Force MaterialsL aboratorfyo r a sampleo f and adviceo n handlingP BT.

PY - 1986/1

Y1 - 1986/1

N2 - This contribution relates new information on the properties of electrically conductive, processible Ni(Pc)/polymer/I2 hybrid materials. Both the temperature and composition dependence of the electrical conductivity of Ni(Pc)/Kevlar/I2 fibres are strongly reminiscent of the behaviour of composites. Using a variant of our fibre spinning methodology, it is also possible to produce Ni(Pc)/Kevlar/I2 ribbons. Polarized resonance Raman spectroscopy indicates that the ribbons are structurally anisotropic (Ni(Pc)I c axes are preferentially aligned in the extrusion direction), while four-probe transport measurements indicate significant anisotropy in the conductivity ( σ{norm of matrix} σhu ≈ 8 where {norm of matrix} denotes the extrusion direction). This anisotropy is nearly temperature independent. Electrically conductive fibres can also be prepared using Nomex or poly(p-phenylene-2,6-benzobisthiazole) (PBT) instead of Kevlar as the host polymer.

AB - This contribution relates new information on the properties of electrically conductive, processible Ni(Pc)/polymer/I2 hybrid materials. Both the temperature and composition dependence of the electrical conductivity of Ni(Pc)/Kevlar/I2 fibres are strongly reminiscent of the behaviour of composites. Using a variant of our fibre spinning methodology, it is also possible to produce Ni(Pc)/Kevlar/I2 ribbons. Polarized resonance Raman spectroscopy indicates that the ribbons are structurally anisotropic (Ni(Pc)I c axes are preferentially aligned in the extrusion direction), while four-probe transport measurements indicate significant anisotropy in the conductivity ( σ{norm of matrix} σhu ≈ 8 where {norm of matrix} denotes the extrusion direction). This anisotropy is nearly temperature independent. Electrically conductive fibres can also be prepared using Nomex or poly(p-phenylene-2,6-benzobisthiazole) (PBT) instead of Kevlar as the host polymer.

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Phthalocyanine-based electrically conductive, processible molecular/macromolecular hybrid materials

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