Photoreductive chlorine elimination from a Ni(iii)Cl2complex supported by a tetradentate pyridinophane ligand

Hanah Na, Michael B. Watson, Fengzhi Tang, Nigam P. Rath, Liviu M. Mirica

Research output: Contribution to journalArticlepeer-review

Abstract

Herein we report the isolation, characterization, and photoreactivity of a stable NiIIIdichloride complex supported by a tetradentate pyridinophane N-donor ligand. Upon irradiation, this complex undergoes an efficient photoreductive chlorine elimination reaction, both in solution and the solid-state. Subsequently, the NiIIICl2species can be regeneratedviaa reaction with PhICl2

Original languageEnglish (US)
Pages (from-to)7264-7267
Number of pages4
JournalChemical Communications
Volume57
Issue number59
DOIs
StatePublished - Jul 28 2021

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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