Pd/C-catalyzed reactions of HMF: Decarbonylation, hydrogenation, and hydrogenolysis

Joyee Mitra, Xiaoyuan Zhou, Thomas Rauchfuss

Research output: Contribution to journalArticlepeer-review


The diverse reactivity of 5-hydroxymethylfural (HMF) in Pd/C-catalyzed reactions is described with emphasis on the role of additives that affect selectivity. Three broad reactions are examined: decarbonylation, hydrogenation, and hydrogenolysis. Especially striking are the multiple roles of formic acid in hydrogenolysis/ hydrogenation and in suppressing decarbonylation, as illustrated by the conversion of HMF to DMF. Hydrogenation of the furan ring is suppressed by CO2 and carboxylic acids. These results emphasize the utility of Pd/C as a convenient catalyst for upgradation of cellulosic biomass.

Original languageEnglish (US)
Pages (from-to)307-313
Number of pages7
JournalGreen Chemistry
Issue number1
StatePublished - Jan 1 2015

ASJC Scopus subject areas

  • Environmental Chemistry
  • Pollution


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