TY - JOUR
T1 - Path integrals for dissipative systems by tensor multiplication. Condensed phase quantum dynamics for arbitrarily long time
AU - Makarov, Dmitrii E.
AU - Makri, Nancy
PY - 1994/4/29
Y1 - 1994/4/29
N2 - Feynman's influence functional that arises from many-particle environments is nonlocal in time but the nonlocality has finite range, even at very low temperature. Use of our numerically constructed quasi-adiabatic propagators permits large time steps in the path integral, such that the nonlocality of the influence functional spans only a few time steps. We exploit these observations to propose an iterative scheme for the evaluation of path integrals by stepwise multiplication of a propagator tensor, thereby making exact quantum dynamics calculations in condensed phase systems feasible for arbitrarily long times.
AB - Feynman's influence functional that arises from many-particle environments is nonlocal in time but the nonlocality has finite range, even at very low temperature. Use of our numerically constructed quasi-adiabatic propagators permits large time steps in the path integral, such that the nonlocality of the influence functional spans only a few time steps. We exploit these observations to propose an iterative scheme for the evaluation of path integrals by stepwise multiplication of a propagator tensor, thereby making exact quantum dynamics calculations in condensed phase systems feasible for arbitrarily long times.
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U2 - 10.1016/0009-2614(94)00275-4
DO - 10.1016/0009-2614(94)00275-4
M3 - Article
AN - SCOPUS:0001727712
SN - 0009-2614
VL - 221
SP - 482
EP - 491
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 5-6
ER -