TY - JOUR
T1 - Path Integral over Equivalence Classes for Quantum Dynamics with Static Disorder
AU - Makri, Nancy
N1 - Publisher Copyright:
© 2024 American Chemical Society.
PY - 2024/2/8
Y1 - 2024/2/8
N2 - An efficient, fully quantum mechanical, real-time path integral method for including the effects of static disorder in the dynamics of systems coupled to common or local harmonic baths is presented. Rather than performing a large number of demanding calculations for different realizations of the system Hamiltonian, the influence of the bath is captured through a single evaluation of the path sum by grouping the system paths into equivalence classes of fixed system amplitudes. The method is illustrated with several analytical and numerical examples that show a variety of nontrivial effects arising from the interplay among coherence, dissipation, thermal fluctuations, and geometric phases.
AB - An efficient, fully quantum mechanical, real-time path integral method for including the effects of static disorder in the dynamics of systems coupled to common or local harmonic baths is presented. Rather than performing a large number of demanding calculations for different realizations of the system Hamiltonian, the influence of the bath is captured through a single evaluation of the path sum by grouping the system paths into equivalence classes of fixed system amplitudes. The method is illustrated with several analytical and numerical examples that show a variety of nontrivial effects arising from the interplay among coherence, dissipation, thermal fluctuations, and geometric phases.
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U2 - 10.1021/acs.jpclett.3c03555
DO - 10.1021/acs.jpclett.3c03555
M3 - Article
C2 - 38294874
AN - SCOPUS:85184662274
SN - 1948-7185
VL - 15
SP - 1462
EP - 1468
JO - Journal of Physical Chemistry Letters
JF - Journal of Physical Chemistry Letters
IS - 5
ER -