Abstract
Equation presented. A mild and general palladium-catalyzed insertion of 1,2-diethoxy-1,1,2,2-tetramethyldisilane into a variety of aryl bromides affords the aryldimethylsilyl ethers in high yields. Hydrolysis of the ethers under pH-optimized conditions results in the exclusive formation of the desired aryldimethylsilanols.
Original language | English (US) |
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Pages (from-to) | 3483-3486 |
Number of pages | 4 |
Journal | Organic Letters |
Volume | 5 |
Issue number | 19 |
DOIs | |
State | Published - Sep 18 2003 |
ASJC Scopus subject areas
- Biochemistry
- Physical and Theoretical Chemistry
- Organic Chemistry