Oxygen evolution at La1-xBaxCoO3 perovskite-type electrodes

Svetlana Mitrovski, Dragutin M. Dražić

Research output: Contribution to journalArticlepeer-review

Abstract

Perovskite oxides of the type La1-x-BaxCoO3 (x = 0 1, 0.2, 0.4) and La0.8Ca0.2CoO3 were synthesized and tested as oxygen anodes in 1 mol dm-3 NaOH solution at room temperature. The electrodes were prepared by pressing and sintering the synthesized perovskite powders. The roughness factors of the electrodes were determined by Hg-porosimetry and by double layer capacitance measurements. The ones determined by Hg-porosimetry, rs, were found to be in the range 42<-rs<1500, while the ones determined from the double layer capacitance, rDL, were found to be in the range 11<rDL<470. No correlation between the composition of the oxides and the roughness factors was found, whereas the ratio rDL/rs remained approximately constant and amounted to around 0.3 (±10%) for all the electrodes. The behaviour of the electrodes in the oxygen evolution reaction (OER) was studied. All the electrodes showed Tafel slopes of about 60 mV dec-1, whereas the activity in the OER, expressed using the corresponding roughness factors, increased with increasing x and was almost one order of magnitude higher for the Ba-than the Ca-substituted perovskite, for the same degree of substitution, x=0.2. The enhanced activity of the perovskites with higher Ba content was attributed to the higher Co4+ ions content, together with the higher specific activity of these active centres for the OER, determined by cyclic voltammetry.

Original languageEnglish (US)
Pages (from-to)555-564
Number of pages10
JournalJournal of the Serbian Chemical Society
Volume63
Issue number7
StatePublished - 1998
Externally publishedYes

Keywords

  • Oxygen evolution
  • Perovskite
  • Reaction mechanism

ASJC Scopus subject areas

  • Chemistry(all)

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