Abstract
The thioester Ph 2PC 6H 4-2-C (O ) SPh reacts with Fe 2(CO) 9 to give [Ph 2PC 6H 4C(O)]Fe(SPh) (CO) 3, a model for the CO-inhibited active site of the enzyme Hmd. This species, which reversibly decarbonylates to give a diiron derivative, reacts with cyanide to give [[Ph 2PCgH 4C(O)]Fe(SPh)(CN)(CO) 2] -.
Original language | English (US) |
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Pages (from-to) | 3618-3620 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 28 |
Issue number | 13 |
DOIs | |
State | Published - Jul 13 2009 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry