Oxidation of pinacyanol chloride by H₂O₂ catalyzed by Fe^III complexed to tetraamidomacrocyclic ligand: Unusual kinetics and product identification

Keyphrases

• Hydrogen Peroxide 100%
• Fe(III) 100%
• Product Identification 100%
• Pinacyanol 100%
• Kinetic Identification 100%
• Chloride Concentration 18%
• Reaction Rate 12%
• Rate of Increase 12%
• Kinetic Data 12%
• TAML Activators 12%
• Nitrate 6%
• Nitrite 6%
• Catalytic Mechanism 6%
• Density Functional Theory 6%
• Oxalate 6%
• Retardation 6%
• Kinetic Analysis 6%
• First-order Process 6%
• Acetate 6%
• 4-nitrobenzoate 6%
• Acidic pH 6%
• Rate Law 6%
• Fe-N 6%
• Rate Decline 6%
• Oxidative Degradation 6%
• Complex Kinetics 6%
• Catalytic Reaction 6%
• C3-C4 6%
• Formate 6%
• Carbon Mineralization 6%
• Maximal Value 6%
• Minimalistic 6%
• Maleate 6%

Chemistry

• Hydrogen Peroxide 100%
• Kinetics Type 40%
• Nitrite 20%
• Rate Constant 20%
• Density Functional Theory 20%
• Kinetic Method 20%
• Catalytic Reaction 20%
• Formate 20%
• Oxidative Degradation 20%
• Carbon Mineralization 20%
• 2-Nitrobenzoate 20%
• Maleate(2-) 20%
• Oxalic Acid 20%
• formation 20%