TY - JOUR
T1 - Organometallic Ni(ii), Ni(iii), and Ni(iv) complexes relevant to carbon-carbon and carbon-oxygen bond formation reactions
AU - Magallón, C.
AU - Griego, L.
AU - Hu, C. H.
AU - Company, A.
AU - Ribas, X.
AU - Mirica, L. M.
N1 - Publisher Copyright:
© the Partner Organisations.
PY - 2022/3/7
Y1 - 2022/3/7
N2 - Herein, the pyridinophanetetradentate ligand 3,6,9-trimethyl-3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene, PyNMe3, is used to isolate and structurally characterize well-defined organometallic Ni(ii) and Ni(iii) complexes bearing the cycloneophyl fragment, an alkyl/aryl C-donor ligand. Furthermore, spectroscopic and cryo-mass spectrometry studies suggest the formation of a transient Ni(iv) organometallic complex, and its relevance to C-C and C-O bond formation reactivity studies is discussed.
AB - Herein, the pyridinophanetetradentate ligand 3,6,9-trimethyl-3,6,9,15-tetraazabicyclo[9.3.1]pentadeca-1(15),11,13-triene, PyNMe3, is used to isolate and structurally characterize well-defined organometallic Ni(ii) and Ni(iii) complexes bearing the cycloneophyl fragment, an alkyl/aryl C-donor ligand. Furthermore, spectroscopic and cryo-mass spectrometry studies suggest the formation of a transient Ni(iv) organometallic complex, and its relevance to C-C and C-O bond formation reactivity studies is discussed.
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U2 - 10.1039/d1qi01486b
DO - 10.1039/d1qi01486b
M3 - Article
AN - SCOPUS:85125831853
SN - 2052-1545
VL - 9
SP - 1016
EP - 1022
JO - Inorganic Chemistry Frontiers
JF - Inorganic Chemistry Frontiers
IS - 5
ER -