Organometallic chemistry of high-valent Ni(III) and Ni(IV) complexes

Liviu M. Mirica, Sofia M. Smith, Leonel Griego

Research output: Chapter in Book/Report/Conference proceedingChapter


This chapter summarizes the accomplishments made in the past 40 years involving organometallic Ni(III) and Ni(IV) complexes, with a focus on the more recent systems that exhibit rich reactivity profiles. In addition, high-valent non-organometallic Ni complexes proposed to play a role in various organic transformations are also discussed.

Original languageEnglish (US)
Title of host publicationNickel Catalysis in Organic Synthesis
Subtitle of host publicationMethods and Reactions
Number of pages26
ISBN (Electronic)9783527813827
ISBN (Print)9783527344079
StatePublished - Nov 12 2019


  • Cross-coupling reactions
  • High-valent Ni complexes
  • Organometallic catalysis

ASJC Scopus subject areas

  • General Chemistry


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