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On the Stereoselective Opening of Achiral Dioxane Acetals
Scott E. Denmark
, Neil G. Almstead
Chemistry
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Keyphrases
Achiral
100%
Acetal
100%
Stereoselectivity
100%
Dioxane
100%
Ion Pairs
60%
Stoichiometry
40%
Isomerization
40%
Controlled Experiment
40%
Lewis Acids
40%
Trisubstituted
40%
Allyltrimethylsilane
40%
Transseries
40%
Equilibration
20%
Meso
20%
Cis-1
20%
Stereochemical Hypothesis
20%
Kinetic Control
20%
Experimental Variables
20%
Structural Variables
20%
Reactive Ions
20%
Asymmetric Induction
20%
Allylation
20%
Stannanes
20%
Allylmetals
20%
Chiral Acetal
20%
Cis-9
20%
Chemistry
Acetal
100%
Dioxane
100%
Ion Pair
50%
Reaction Stoichiometry
33%
Isomerization
33%
Lewis Acid
33%
Butylstannane
33%
Structure
16%
Stereoselectivity
16%
Allylation
16%
Stannane
16%