Abstract
The stereochemical course of the intramolecular allylsilane‐aldehyde condensation of 1a has been investigated. A modest preference for the product arising from a synclinal orientation of double bonds was observed with Lewis‐acid catalysts. Cyclization induced by fluoride ion resulted in stereochemical reversal.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1655-1660 |
| Number of pages | 6 |
| Journal | Helvetica Chimica Acta |
| Volume | 66 |
| Issue number | 6 |
| DOIs | |
| State | Published - Sep 21 1983 |
ASJC Scopus subject areas
- Catalysis
- Biochemistry
- Drug Discovery
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry