On-chip high speed gas chromatograph (Gc) with carbon nanotube sensors

Adarsh D. Radadia, Richard I. Masel, Michael S. Strano, Mark A. Shannon, Keith Cadwallader

Research output: Contribution to conferencePaperpeer-review

Abstract

A micro-GC allows for small, handheld, low power equipments with on-chip devices for environmental sampling. In order to use a micro-GC as a fast chemical warfare agent scanner in highly industrious places like airports, there is a definite need for reduction in analysis times from the current state of the art. Current technology cannot scan (separate and detect) air samples in relatively short times (∼ 4 seconds). High speed analysis GC requires 1) a continuous sampling part, 2) a preconcentration part, 3) micro-columns with high separation efficiency and resolution ability and 4) a detector with fast analysis time. We use standard microfabrication techniques to create each of the components and test individual performance. Integration of the fabricated parts will not be demonstrated. A MEMS pump with a fluctuating polyimide membrane is fabricated to form the continuous sampling component of the GC. Preconcentration principle is demonstrated in a microfluidic processor with valves using metal-organic framework molecules as the adsorbing species. Micro-columns are fabricated in silicon using DRIE technique. High resolution columns are fabricated after studying effects of 1) various micro-channel bend geometries and 2) micro-channel configurations on chip. The detector side effort is focused on building a carbon nanotube based chemi-sensors. Carbon nanotubes are highly promising materials for sensing chemical species like thionyl chloride and dimethylmethylphosphonate, a simulant for chemical warfare agent sarin. Results of individual operational components are evaluated using an ordinary modified GC.

Original languageEnglish (US)
Number of pages1
StatePublished - Dec 1 2005
Externally publishedYes
Event05AIChE: 2005 AIChE Annual Meeting and Fall Showcase - Cincinnati, OH, United States
Duration: Oct 30 2005Nov 4 2005

Other

Other05AIChE: 2005 AIChE Annual Meeting and Fall Showcase
Country/TerritoryUnited States
CityCincinnati, OH
Period10/30/0511/4/05

ASJC Scopus subject areas

  • Engineering(all)

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