@article{b1bea00c74594d4aa69f1d85ac1e2299,
title = "Observation of two paramagnetic species in electron transfer reactions within cesium modified X and Y zeolites",
abstract = "Tetrachloro-1,2-benzoquinone (o-chloranyl) has been used as a probe molecule to examine its interaction with catalytically active basic sites of cesium modified X and Y zeolites. Applying CW and pulsed EPR we were able to detect for the first time two paramagnetic species formed in the electron transfer reaction of active sites with o-chloranyl. One species is an anion-radical of o-chloranyl trapped in zeolite cage in the surrounding of alkaline ions. The other one is located on the zeolite lattice and comprises a center with a hole localized on oxygen(s) adjacent to the aluminum carrying about 50% of unpaired spin density.",
author = "Samoilova, {Rimma I.} and Shubin, {Alexander A.} and Bowman, {Michael K.} and J{\"u}rgen H{\"u}ttermann and Dikanov, {Sergei A.}",
note = "Funding Information: S.A.D. acknowledges receipt of the Alexander von Humboldt Foundation Research Fellow Award (06/01/92 to 10/31/93). R.I.S. thanks the Deutsche Forschungs-gemeinschaft for grants supporting her sojourns (in 1993 and 1999) at Saarland University. Part of this work was sponsored by the US Department of Energy under Contract DE-AC06-76RLO 1830 and by Associated Western Universities, Northwest Division (AWU NW), under Grant DE-FG06-89ER-75522 or DE-FG06-92RL-12451 with the US Department of Energy. S.A.D. and R.I.S. acknowledge a Faculty Fellowship from the Associated Western Universities, R.I.S. is grateful for participation in the SABIT program. S.A.D. thanks Alexander von Humboldt Foundation for the support of his soujorn at Saarland University in June 1999.",
year = "2000",
month = jan,
day = "21",
doi = "10.1016/S0009-2614(99)01342-1",
language = "English (US)",
volume = "316",
pages = "404--410",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "5-6",
}