Nonclassical Polysulfide Complexes: Cage and Ring Compounds [(MeCp)Ru(PPh3)]2Sx(x = 6, 4)

Jayantha Amarasekera, Thomas Rauchfuss, Arnold L. Rheingold

Research output: Contribution to journalArticlepeer-review

Abstract

Aggregates of main-group elements are rich sources of ligands in transition-metal chemistry. Two topical classes of such ligands are polyatomic main group anions and cations. Metal polysulfide complexes may be viewed as derivatives of the simple Zintl ions Sx 2-. In principle such metalla-Zintl complexes would adopt cage and ring structures of the Gillespie type when rendered electron deficient. Previous work has shown, however, that electron deficiency in metal sulfides stabilizes terminal mono- and disulfido ligands. We now report results obtained in the course of our studies on organoruthenium sulfides that show a relationship between metallapolysulfides and polysulfur cations.

Original languageEnglish (US)
Pages (from-to)2017-2018
Number of pages2
JournalInorganic Chemistry
Volume26
Issue number13
DOIs
StatePublished - Jan 1 1987

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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