Nickel-Carbon Bond Oxygenation with Green Oxidants via High-Valent Nickel Species

Keyphrases

• 1,4,7-triazacyclononane 33%
• Biomimetic 33%
• Bond Cleavage 33%
• Bond-forming 33%
• Bond-forming Reactions 33%
• C-O Bond Formation 33%
• Carbon Bond 100%
• Catalytic Transformation 33%
• Chemoselectivity 33%
• Computational Study 33%
• Coordinating Solvents 33%
• Cumene Hydroperoxide 33%
• Dimethyl 33%
• Dioxygen 33%
• Eyring Analysis 33%
• First-order 33%
• Formation Reaction 33%
• Green Oxidant 100%
• Heterotic 33%
• High-valent 66%
• High-valent Metal 33%
• High-valent Nickel 100%
• Hydrogen Peroxide 33%
• Inner-sphere Mechanism 33%
• Isotopically Labeled 33%
• Kinetic Study 33%
• Mechanistic Studies 33%
• Meta-chloroperoxybenzoic Acid (MCPBA) 33%
• Metal-oxygen Intermediates 33%
• Ni(II) 100%
• Nickel Species 100%
• Oxidative Transformation 33%
• Oxygen Species 33%
• Oxygenase 33%
• Oxygenation 100%
• Peroxidase 33%
• Peroxide 33%
• Rate-determining Step 33%
• Reaction Conditions 33%
• Reductive Elimination 33%
• Second-order Reaction 33%
• Solvent Conditions 33%
• Tert-butyl 33%

Chemistry

• Biomimetics 100%
• Chemoselectivity 100%
• Cumene Hydroperoxide 100%
• Dioxygen 100%
• Hydrogen Peroxide 100%
• Kinetic Study 100%
• Mechanistic Study 100%
• Metallocene 100%
• Oxygenase 100%
• Peroxidase 100%
• Rate-Determining Step 100%
• Reductive Elimination Reaction 100%