New Organic Polymers and Molecules with Very High Spin States

Dennis A. Dougherty; S. Joshua Jacobs; Scott K. Silverman; Michael M. Murray; David A. Shultz; Anthony P. West; Jeffrey A. Clites

doi:10.1080/10587259308035719

New Organic Polymers and Molecules with Very High Spin States

Dennis A. Dougherty, S. Joshua Jacobs, Scott K. Silverman, Michael M. Murray, David A. Shultz, Anthony P. West, Jeffrey A. Clites

Research output: Contribution to journal › Article › peer-review

Abstract

A number of new organic tetraradicals with quintet ground states have been prepared. Along with their intrinsic significance, these structures provide valuable tests of certain design principles for the construction of organic magnetic materials. The tetraradicals all follow the “bis(TMM)” approach, which promises to provide a wealth of Information on spin preferences in organic structures. Efforts to prepare prototypes of the polaronic ferromagnet are also described. Current work is aimed at evaluating the role of bipolaron formation in such Systems, in an effort to increase the absolute spin concentration.

Original language	English (US)
Pages (from-to)	289-304
Number of pages	16
Journal	Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
Volume	232
Issue number	1
DOIs	https://doi.org/10.1080/10587259308035719
State	Published - Aug 1 1993
Externally published	Yes

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Condensed Matter Physics

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10.1080/10587259308035719

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AU - Dougherty, Dennis A.

AU - Jacobs, S. Joshua

AU - Silverman, Scott K.

AU - Murray, Michael M.

AU - Shultz, David A.

AU - West, Anthony P.

AU - Clites, Jeffrey A.

PY - 1993/8/1

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AB - A number of new organic tetraradicals with quintet ground states have been prepared. Along with their intrinsic significance, these structures provide valuable tests of certain design principles for the construction of organic magnetic materials. The tetraradicals all follow the “bis(TMM)” approach, which promises to provide a wealth of Information on spin preferences in organic structures. Efforts to prepare prototypes of the polaronic ferromagnet are also described. Current work is aimed at evaluating the role of bipolaron formation in such Systems, in an effort to increase the absolute spin concentration.

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New Organic Polymers and Molecules with Very High Spin States

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