Near-IR Fourier transform Raman spectroscopy of photolabile organocobalt B12 and model compounds. Identification of the Co-C bond stretch in cobalamins

Shuming Nie; Patricia A. Marzilli; Luigi G. Marzilli; Nai Teng Yu

doi:10.1039/C39900000770

Near-IR Fourier transform Raman spectroscopy of photolabile organocobalt B₁₂ and model compounds. Identification of the Co-C bond stretch in cobalamins

Shuming Nie
, Patricia A. Marzilli
, Luigi G. Marzilli
, Nai Teng Yu

Research output: Contribution to journal › Article › peer-review

Abstract

The frequency of the Raman-active Co-C bond stretch in photolabile methylcoenzyme B₁₂ has been conclusively determined by the new technique of near-IR Fourier transform (FT) Raman spectroscopy to be 500 cm ^-1 for methylcobalamin and 470 Cm^-1 for deuteriated methyl (CD₃^-) cobalamin.

Original language	English (US)
Pages (from-to)	770-771
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	10
DOIs	https://doi.org/10.1039/C39900000770
State	Published - 1990
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39900000770

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Near-IR Fourier transform Raman spectroscopy of photolabile organocobalt B₁₂ and model compounds. Identification of the Co-C bond stretch in cobalamins. / Nie, Shuming; Marzilli, Patricia A.; Marzilli, Luigi G. et al.
In: Journal of the Chemical Society D: Chemical Communications, No. 10, 1990, p. 770-771.

Research output: Contribution to journal › Article › peer-review

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abstract = "The frequency of the Raman-active Co-C bond stretch in photolabile methylcoenzyme B12 has been conclusively determined by the new technique of near-IR Fourier transform (FT) Raman spectroscopy to be 500 cm -1 for methylcobalamin and 470 Cm-1 for deuteriated methyl (CD3-) cobalamin.",

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AU - Yu, Nai Teng

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AB - The frequency of the Raman-active Co-C bond stretch in photolabile methylcoenzyme B12 has been conclusively determined by the new technique of near-IR Fourier transform (FT) Raman spectroscopy to be 500 cm -1 for methylcobalamin and 470 Cm-1 for deuteriated methyl (CD3-) cobalamin.

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