Near-IR Fourier transform Raman spectroscopy of photolabile organocobalt B12 and model compounds. Identification of the Co-C bond stretch in cobalamins

Shuming Nie, Patricia A. Marzilli, Luigi G. Marzilli, Nai Teng Yu

Research output: Contribution to journalArticlepeer-review

Abstract

The frequency of the Raman-active Co-C bond stretch in photolabile methylcoenzyme B12 has been conclusively determined by the new technique of near-IR Fourier transform (FT) Raman spectroscopy to be 500 cm -1 for methylcobalamin and 470 Cm-1 for deuteriated methyl (CD3-) cobalamin.

Original languageEnglish (US)
Pages (from-to)770-771
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number10
DOIs
StatePublished - Dec 1 1990
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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