Near-infrared spectroscopy of H3+ above the barrier to linearity

Jennifer L. Gottfried, Benjamin J. McCall, Takeshi Oka

Research output: Contribution to journalArticlepeer-review

Abstract

The transitions of H3+ ions above the linearity barrier were investigated by studying the absorption spectrum in the near-infrared region. The observed transitions were found to be 4600 times weaker than the fundamental band, probe energy levels above 10000 cm-1. The incorporation of adiabatic and relativistic corrections revealed the extent of higher-order effects.

Original languageEnglish (US)
Pages (from-to)10890-10899
Number of pages10
JournalJournal of Chemical Physics
Volume118
Issue number24
DOIs
StatePublished - Jun 22 2003

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Near-infrared spectroscopy of H<sub>3</sub><sup>+</sup> above the barrier to linearity'. Together they form a unique fingerprint.

Cite this