Nanosecond Metal-to-Ligand Charge-Transfer State in an Fe(II) Chromophore: Lifetime Enhancement via Nested Potentials

Keyphrases

• Chromophore 100%
• Fe(II) 100%
• Ligand-to-metal Charge Transfer 100%
• Lifetime Enhancement 100%
• Charge Transfer States 66%
• Long-lived 66%
• Fe(II) Complex 66%
• Low-lying 33%
• Density Functional Calculations 33%
• N-of-1 33%
• Chelates 33%
• Axial Ligand 33%
• Macrocycles 33%
• Air-stable 33%
• Tetragonal 33%
• Potential Energy Surface 33%
• Fe-N 33%
• Photophysical Properties 33%
• Solvent Environment 33%
• Octahedral Geometry 33%
• Rigidity Results 33%
• T2g Orbital 33%
• Tetraene 33%
• Strong Donor 33%
• Lewis Acid-base Interaction 33%
• Ligand Field Strength 33%
• Cyano Ligand 33%

Chemistry

• Chromophore 100%
• Charge Transfer State 100%
• Iron Complex 50%
• Base 25%
• Density Functional Theory 25%
• Lewis Acid 25%
• Donor 25%
• Macrocycle 25%
• Potential Energy Surface 25%