N-Methylimidazole Mediated Chemistry of Transition Metal Phenylthiolates. The Isolation of the Perthiolate Salts [M(N-MeIm)6](S2Ph)2

Ulrike Krautscheid; Somanath Dev; Harald Krautscheid; Partha P. Paul; Scott R. Wilson; Thomas B. Rauchfuss

doi:10.1515/znb-1993-0515

N-Methylimidazole Mediated Chemistry of Transition Metal Phenylthiolates. The Isolation of the Perthiolate Salts [M(N-MeIm)₆](S₂Ph)₂

Ulrike Krautscheid, Somanath Dev, Harald Krautscheid, Partha P. Paul, Scott R. Wilson, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Salts of the composition [M(N-MeIm)₆](SPh)₂ (M = Mn, Ni; N-Melm = N-methylimidazole) were prepared by dissolution of the metal powders with N-Melm solutions of Ph₂S₂. X-ray crystallographic examination established that these salts indeed feature uncoordinated PhS⁻. The salts [M(N-MeIm)₆](SPh)₂ (M = Mn, Ni) react with S₈ to give [M(N-MeIm)₆]S₈ via the intermediacy of the perthiolate salts [M(N-MeIm)₆](S₂Ph)₂.

Original language	English (US)
Pages (from-to)	653-658
Number of pages	6
Journal	Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume	48
Issue number	5
DOIs	https://doi.org/10.1515/znb-1993-0515
State	Published - May 1 1993

Keywords

Imidazole
Metal Powders
Oxidation
Perthiolate
Thiolate

ASJC Scopus subject areas

General Chemistry

Online availability

10.1515/znb-1993-0515

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N-Methylimidazole Mediated Chemistry of Transition Metal Phenylthiolates. The Isolation of the Perthiolate Salts [M(N-MeIm)₆](S₂Ph)₂ . / Krautscheid, Ulrike; Dev, Somanath; Krautscheid, Harald et al.
In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 48, No. 5, 01.05.1993, p. 653-658.

Research output: Contribution to journal › Article › peer-review

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title = "N-Methylimidazole Mediated Chemistry of Transition Metal Phenylthiolates. The Isolation of the Perthiolate Salts [M(N-MeIm)6](S2Ph)2 ",

abstract = "Salts of the composition [M(N-MeIm)6](SPh)2 (M = Mn, Ni; N-Melm = N-methylimidazole) were prepared by dissolution of the metal powders with N-Melm solutions of Ph2S2. X-ray crystallographic examination established that these salts indeed feature uncoordinated PhS−. The salts [M(N-MeIm)6](SPh)2 (M = Mn, Ni) react with S8 to give [M(N-MeIm)6]S8 via the intermediacy of the perthiolate salts [M(N-MeIm)6](S2Ph)2.",

keywords = "Imidazole, Metal Powders, Oxidation, Perthiolate, Thiolate",

author = "Ulrike Krautscheid and Somanath Dev and Harald Krautscheid and Paul, {Partha P.} and Wilson, {Scott R.} and Rauchfuss, {Thomas B.}",

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AU - Krautscheid, Ulrike

AU - Dev, Somanath

AU - Krautscheid, Harald

AU - Paul, Partha P.

AU - Wilson, Scott R.

AU - Rauchfuss, Thomas B.

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AB - Salts of the composition [M(N-MeIm)6](SPh)2 (M = Mn, Ni; N-Melm = N-methylimidazole) were prepared by dissolution of the metal powders with N-Melm solutions of Ph2S2. X-ray crystallographic examination established that these salts indeed feature uncoordinated PhS−. The salts [M(N-MeIm)6](SPh)2 (M = Mn, Ni) react with S8 to give [M(N-MeIm)6]S8 via the intermediacy of the perthiolate salts [M(N-MeIm)6](S2Ph)2.

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