Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

S. A. Dikanov; A. V. Astashkin; Yu D. Tsvetkov

doi:10.1016/0009-2614(84)80062-7

Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

S. A. Dikanov
, A. V. Astashkin
, Yu D. Tsvetkov

Research output: Contribution to journal › Article › peer-review

Abstract

Electron spin echo modulation effects have been investigated in trans bis(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals involving ¹⁴N or ¹⁵N nuclei in different positions. The modulation frequencies are shown to be the nitrogen nuclear transition frequencies in radical fragments at m_S = 0 of a triplet electronic spin. Quadrupole splitting parameters for these nitrogen nuclei have been determined.

Original language	English (US)
Pages (from-to)	451-455
Number of pages	5
Journal	Chemical Physics Letters
Volume	105
Issue number	4
DOIs	https://doi.org/10.1016/0009-2614(84)80062-7
State	Published - Mar 23 1984
Externally published	Yes

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General Physics and Astronomy
Physical and Theoretical Chemistry

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abstract = "Electron spin echo modulation effects have been investigated in trans bis(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals involving 14N or 15N nuclei in different positions. The modulation frequencies are shown to be the nitrogen nuclear transition frequencies in radical fragments at mS = 0 of a triplet electronic spin. Quadrupole splitting parameters for these nitrogen nuclei have been determined.",

author = "Dikanov, \{S. A.\} and Astashkin, \{A. V.\} and Tsvetkov, \{Yu D.\}",

year = "1984",

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doi = "10.1016/0009-2614(84)80062-7",

language = "English (US)",

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journal = "Chemical Physics Letters",

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T1 - Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

AU - Dikanov, S. A.

AU - Astashkin, A. V.

AU - Tsvetkov, Yu D.

PY - 1984/3/23

Y1 - 1984/3/23

N2 - Electron spin echo modulation effects have been investigated in trans bis(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals involving 14N or 15N nuclei in different positions. The modulation frequencies are shown to be the nitrogen nuclear transition frequencies in radical fragments at mS = 0 of a triplet electronic spin. Quadrupole splitting parameters for these nitrogen nuclei have been determined.

AB - Electron spin echo modulation effects have been investigated in trans bis(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals involving 14N or 15N nuclei in different positions. The modulation frequencies are shown to be the nitrogen nuclear transition frequencies in radical fragments at mS = 0 of a triplet electronic spin. Quadrupole splitting parameters for these nitrogen nuclei have been determined.

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ER -

Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

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