Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

S. A. Dikanov; A. V. Astashkin; Yu D. Tsvetkov

doi:10.1016/0009-2614(84)80062-7

Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

S. A. Dikanov, A. V. Astashkin, Yu D. Tsvetkov

Research output: Contribution to journal › Article › peer-review

Abstract

Electron spin echo modulation effects have been investigated in trans bis(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals involving ¹⁴N or ¹⁵N nuclei in different positions. The modulation frequencies are shown to be the nitrogen nuclear transition frequencies in radical fragments at m_S = 0 of a triplet electronic spin. Quadrupole splitting parameters for these nitrogen nuclei have been determined.

Original language	English (US)
Pages (from-to)	451-455
Number of pages	5
Journal	Chemical Physics Letters
Volume	105
Issue number	4
DOIs	https://doi.org/10.1016/0009-2614(84)80062-7
State	Published - Mar 23 1984
Externally published	Yes

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Online availability

10.1016/0009-2614(84)80062-7

Library availability

Discover UIUC Full Text

Cite this

@article{85ec892999e14169b4350642f149de1c,

title = "Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals",

abstract = "Electron spin echo modulation effects have been investigated in trans bis(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals involving 14N or 15N nuclei in different positions. The modulation frequencies are shown to be the nitrogen nuclear transition frequencies in radical fragments at mS = 0 of a triplet electronic spin. Quadrupole splitting parameters for these nitrogen nuclei have been determined.",

author = "Dikanov, {S. A.} and Astashkin, {A. V.} and Tsvetkov, {Yu D.}",

year = "1984",

month = mar,

day = "23",

doi = "10.1016/0009-2614(84)80062-7",

language = "English (US)",

volume = "105",

pages = "451--455",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "4",

}

TY - JOUR

T1 - Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

AU - Dikanov, S. A.

AU - Astashkin, A. V.

AU - Tsvetkov, Yu D.

PY - 1984/3/23

Y1 - 1984/3/23

N2 - Electron spin echo modulation effects have been investigated in trans bis(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals involving 14N or 15N nuclei in different positions. The modulation frequencies are shown to be the nitrogen nuclear transition frequencies in radical fragments at mS = 0 of a triplet electronic spin. Quadrupole splitting parameters for these nitrogen nuclei have been determined.

AB - Electron spin echo modulation effects have been investigated in trans bis(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals involving 14N or 15N nuclei in different positions. The modulation frequencies are shown to be the nitrogen nuclear transition frequencies in radical fragments at mS = 0 of a triplet electronic spin. Quadrupole splitting parameters for these nitrogen nuclei have been determined.

UR - http://www.scopus.com/inward/record.url?scp=48749137445&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=48749137445&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(84)80062-7

DO - 10.1016/0009-2614(84)80062-7

M3 - Article

AN - SCOPUS:48749137445

SN - 0009-2614

VL - 105

SP - 451

EP - 455

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4

ER -

Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

Abstract

ASJC Scopus subject areas

Online availability

Library availability

Related links

Fingerprint

Cite this