Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

S. A. Dikanov, A. V. Astashkin, Yu D. Tsvetkov

Research output: Contribution to journalArticlepeer-review

Abstract

Electron spin echo modulation effects have been investigated in trans bis(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals involving 14N or 15N nuclei in different positions. The modulation frequencies are shown to be the nitrogen nuclear transition frequencies in radical fragments at mS = 0 of a triplet electronic spin. Quadrupole splitting parameters for these nitrogen nuclei have been determined.

Original languageEnglish (US)
Pages (from-to)451-455
Number of pages5
JournalChemical Physics Letters
Volume105
Issue number4
DOIs
StatePublished - Mar 23 1984
Externally publishedYes

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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