Modulating Noncovalent Cross-links with Molecular Switches

Eric S. Epstein, Luca Martinetti, Ravichandran H. Kollarigowda, Olivia Carey-De La Torre, Jeffrey S. Moore, Randy H. Ewoldt, Paul V. Braun

Research output: Contribution to journalArticlepeer-review

Abstract

Spiropyran molecular switches, in conjunction with transition metal ions, are shown to operate as reversible polymer cross-linkers. Solutions containing a spiropyran-functionalized polymer and transition metal ions underwent reversible thermally triggered (light-triggered) transient network formation (disruption) driven by the association (dissociation) of metal-ligand cross-links. Heat triggers metal-ion-mediated cross-linking via thermal isomerization of spiropyran to its open, merocyanine form, and exposure to visible light triggers dissociation of polymer cross-links. Cross-linking is found to depend on both the valence of the ion as well as the molar ratio of spiropyran to metal salt. We envision this to be a starting point for the design of many types of reversible, stimuli-responsive polymers, utilizing the fact that spiropyrans have been shown to respond to a variety of stimuli including heat, light, pH, and mechanical force.

Original languageEnglish (US)
Pages (from-to)3597-3604
Number of pages8
JournalJournal of the American Chemical Society
Volume141
Issue number8
DOIs
StatePublished - Feb 27 2019

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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