MODEL FOR FILM FORMATION AND CURRENT OSCILLATIONS IN THE ELECTRODISSOLUTION OF A COPPER ROTATING DISK ELECTRODE IN ACIDIC CHLORIDE MEDIA.

Arne J. Pearlstein; H. P. Lee; Ken Nobe

MODEL FOR FILM FORMATION AND CURRENT OSCILLATIONS IN THE ELECTRODISSOLUTION OF A COPPER ROTATING DISK ELECTRODE IN ACIDIC CHLORIDE MEDIA.

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Abstract

A mathematical model of the current oscillations observed in the potentiostatic electrodissolution of a Cu rotating disk electrode is described and analyzed. The model predicts the conditions under which a CuCl film of constant thickness exists on the electrode surface, along with the conditions under which the film thickness and current density will be oscillatory (in some cases periodic) functions of time. The theoretical predictions are in excellent qualitative agreement with the experimental results.

Original language	English (US)
Journal	Annual Meeting - American Institute of Chemical Engineers
State	Published - 1984
Externally published	Yes

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General Engineering

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title = "MODEL FOR FILM FORMATION AND CURRENT OSCILLATIONS IN THE ELECTRODISSOLUTION OF A COPPER ROTATING DISK ELECTRODE IN ACIDIC CHLORIDE MEDIA.",

abstract = "A mathematical model of the current oscillations observed in the potentiostatic electrodissolution of a Cu rotating disk electrode is described and analyzed. The model predicts the conditions under which a CuCl film of constant thickness exists on the electrode surface, along with the conditions under which the film thickness and current density will be oscillatory (in some cases periodic) functions of time. The theoretical predictions are in excellent qualitative agreement with the experimental results.",

author = "Pearlstein, {Arne J.} and Lee, {H. P.} and Ken Nobe",

year = "1984",

language = "English (US)",

journal = "Annual Meeting - American Institute of Chemical Engineers",

issn = "0196-7282",

}

TY - JOUR

T1 - MODEL FOR FILM FORMATION AND CURRENT OSCILLATIONS IN THE ELECTRODISSOLUTION OF A COPPER ROTATING DISK ELECTRODE IN ACIDIC CHLORIDE MEDIA.

AU - Pearlstein, Arne J.

AU - Lee, H. P.

AU - Nobe, Ken

PY - 1984

Y1 - 1984

N2 - A mathematical model of the current oscillations observed in the potentiostatic electrodissolution of a Cu rotating disk electrode is described and analyzed. The model predicts the conditions under which a CuCl film of constant thickness exists on the electrode surface, along with the conditions under which the film thickness and current density will be oscillatory (in some cases periodic) functions of time. The theoretical predictions are in excellent qualitative agreement with the experimental results.

AB - A mathematical model of the current oscillations observed in the potentiostatic electrodissolution of a Cu rotating disk electrode is described and analyzed. The model predicts the conditions under which a CuCl film of constant thickness exists on the electrode surface, along with the conditions under which the film thickness and current density will be oscillatory (in some cases periodic) functions of time. The theoretical predictions are in excellent qualitative agreement with the experimental results.

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UR - http://www.scopus.com/inward/citedby.url?scp=0021636208&partnerID=8YFLogxK

M3 - Conference article

AN - SCOPUS:0021636208

SN - 0196-7282

JO - Annual Meeting - American Institute of Chemical Engineers

JF - Annual Meeting - American Institute of Chemical Engineers

ER -

MODEL FOR FILM FORMATION AND CURRENT OSCILLATIONS IN THE ELECTRODISSOLUTION OF A COPPER ROTATING DISK ELECTRODE IN ACIDIC CHLORIDE MEDIA.

Abstract

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