We report the structural transition of a phosphonium ionic liquid-based microemulsion from the bulk to nanoconfined between atomically flat micas. Upon the nanoconfinement, we observed a firmly surface-adsorbed ionic liquid film that stabilizes the nanoconfined microemulsion. Further confinement (<11 nm) induces rearrangements in the microemulsion culminating into two well-ordered layers with slow dynamics.

Original languageEnglish (US)
Pages (from-to)9609-9613
Number of pages5
JournalSoft Matter
Issue number47
StatePublished - 2019

ASJC Scopus subject areas

  • General Chemistry
  • Condensed Matter Physics


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